Chile is going to have its hands full with Brazil to start the 2014 World Cup Round of 16.

68 times the two teams have played head-to-head and 48 times the Brazilians have been victorious, compared to 13 draws and 7 Chilean wins. As the top team in Group A, the host nation and Chile will play for a chance to move on to the Round of 8.

CLICK HERE to watch the match live online via WatchESPN. The game starts at 12 p.m. ET and coverage beings at 11:30 a.m.

According to FIFA.com, Estadio Mineirao, an arena built in 1965 that seats 58,170 people, will host Saturday's match. The city of Belo Horizonte will be hot and have few clouds in the sky to buffer the mid-90s temperature, according to Weather.com.

Surprisingly, Brazil only advanced at the top of their group by holding a goal differential advantage over Mexico. When those two played in the group stage, they finished in a draw, freezing Brazil's chances to advance at the time. To close out the group stage, Brazil beat Cameroon 4-1 to lock up the top spot in Group A.

In their second match of the World Cup, Chile beat Spain 2-0 to hand the reigning champions their second loss in as many games, eliminating them from the tournament. But Chile could not sweep their group and lost to the Netherlands, who ended up with nine points and a +7 goal differential.

The Round of 16 is the first of the knockout rounds and now every team is just four wins away from hoisting the World Cup trophy. Unlike the group stage, knockout games cannot end in a draw. If the score is tied after the final whistle, the game will go into as many as two bonus periods (like overtime) of 15 minutes each. If the game is still tied afterward, the match will be decided by a penalty kick shootout.